\u4ece\u8868\u4e2d\u53ef\u89c1\uff0cTMEDA\u4e0d\u4ec5\u8d77\u53d1\u5feb\u3001\u56fa\u5316\u5feb\uff0c\u8fd8\u80fd\u83b7\u5f97\u66f4\u4f4e\u5bc6\u5ea6\u3001\u66f4\u5747\u5300\u7684\u6ce1\u6cab\u7ed3\u6784\u3002\u5c24\u5176\u5728\u8f6f\u8d28\u6ce1\u6cab\u4e2d\uff0c\u5b83\u7684\u8868\u73b0\u582a\u79f0\u201c\u6559\u79d1\u4e66\u7ea7\u522b\u201d\u3002\u66f4\u96be\u5f97\u7684\u662f\uff0c\u5c3d\u7ba1\u50ac\u5316\u6d3b\u6027\u9ad8\uff0c\u4f46\u5176\u7528\u91cf\u53cd\u800c\u6bd4\u4f20\u7edf\u53d4\u80fa\u66f4\u5c11\uff0c\u7ecf\u6d4e\u6027\u66f4\u4f18\u3002<\/p>\n
\u4e94\u3001\u5e94\u7528\u573a\u666f\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u751f\u4ea7\u7ebf<\/p>\n
TMEDA\u7684\u5e94\u7528\uff0c\u65e9\u5df2\u8d70\u51fa\u5b9e\u9a8c\u5ba4\uff0c\u6df1\u5165\u805a\u6c28\u916f\u5de5\u4e1a\u7684\u5404\u4e2a\u89d2\u843d\u3002<\/p>\n
- \n
- \n
\u8f6f\u8d28\u6ce1\u6cab\uff1a\u7528\u4e8e\u5e8a\u57ab\u3001\u6c99\u53d1\u3001\u6c7d\u8f66\u5750\u57ab\u7b49\u3002\u52a0\u51650.5\u20131.0 pphp TMEDA\uff0c\u53ef\u663e\u8457\u7f29\u77ed\u751f\u4ea7\u7ebf\u8282\u62cd\uff0c\u63d0\u9ad8\u4ea7\u80fd\u3002\u67d0\u56fd\u5185\u5927\u578b\u5bb6\u5177\u5382\u53cd\u9988\uff0c\u4f7f\u7528TMEDA\u540e\uff0c\u53d1\u6ce1\u7ebf\u901f\u5ea6\u63d0\u534720%\uff0c\u5e9f\u54c1\u7387\u4e0b\u964d15%\u3002\n<\/li>\n
- \n
\u534a\u786c\u8d28\u6ce1\u6cab\uff1a\u7528\u4e8e\u6c7d\u8f66\u4eea\u8868\u677f\u3001\u95e8\u677f\u7b49\u3002\u8fd9\u7c7b\u6ce1\u6cab\u8981\u6c42\u201c\u76ae\u786c\u82af\u8f6f\u201d\uff0c\u5bf9\u53d1\u6ce1\u4e0e\u51dd\u80f6\u7684\u5e73\u8861\u6781\u4e3a\u654f\u611f\u3002TMEDA\u7684\u9009\u62e9\u6027\u50ac\u5316\u7279\u6027\uff0c\u6b63\u597d\u6ee1\u8db3\u8fd9\u4e00\u9700\u6c42\u3002\n<\/li>\n
- \n
\u55b7\u6d82\u805a\u6c28\u916f\uff1a\u73b0\u573a\u65bd\u5de5\u8981\u6c42\u5feb\u901f\u56fa\u5316\u3002TMEDA\u80fd\u5e2e\u52a9\u4f53\u7cfb\u5728\u51e0\u79d2\u5185\u5b8c\u6210\u8d77\u53d1\uff0c\u907f\u514d\u6d41\u6dcc\uff0c\u63d0\u5347\u65bd\u5de5\u6548\u7387\u3002\n<\/li>\n
- \n
\u7279\u79cd\u6ce1\u6cab\uff1a\u5982\u963b\u71c3\u3001\u9ad8\u56de\u5f39\u6ce1\u6cab\u3002\u5728\u8fd9\u4e9b\u9ad8\u9644\u52a0\u503c\u4ea7\u54c1\u4e2d\uff0cTMEDA\u5e38\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\uff08\u5982\u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff09\u590d\u914d\uff0c\u5b9e\u73b0\u201c\u53d1\u6ce1-\u51dd\u80f6\u201d\u53cc\u50ac\u5316\u8c03\u63a7\u3002\n<\/li>\n<\/ol>\n
\u5f53\u7136\uff0cTMEDA\u4e5f\u4e0d\u662f\u201c\u5b8c\u7f8e\u4fa0\u5ba2\u201d\u3002\u5b83\u7684\u4e3b\u8981\u7f3a\u70b9\u662f\u6c14\u5473\u8f83\u5927\uff0c\u957f\u671f\u63a5\u89e6\u5bf9\u547c\u5438\u9053\u6709\u523a\u6fc0\u3002\u56e0\u6b64\uff0c\u5728\u5bc6\u95ed\u7a7a\u95f4\u4f7f\u7528\u65f6\u9700\u52a0\u5f3a\u901a\u98ce\u3002\u6b64\u5916\uff0c\u5b83\u6613\u5438\u6c34\uff0c\u50a8\u5b58\u65f6\u9700\u5bc6\u5c01\u9632\u6f6e\u3002<\/p>\n
\u516d\u3001\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\u7684\u201c\u534e\u5c71\u8bba\u5251\u201d<\/p>\n
\u5728\u50ac\u5316\u5242\u7684\u6c5f\u6e56\u4e2d\uff0cTMEDA\u5e38\u4e0e\u51e0\u4f4d\u201c\u9ad8\u624b\u201d\u8fc7\u62db\uff1a<\/p>\n
![\"\"](\"\/images\/29.jpg\")
<\/p>\n\u5728\u50ac\u5316\u5242\u7684\u6c5f\u6e56\u4e2d\uff0cTMEDA\u5e38\u4e0e\u51e0\u4f4d\u201c\u9ad8\u624b\u201d\u8fc7\u62db\uff1a<\/p>\n
- \n
- \u4e09\u4e9a\u4e59\u57fa\u4e8c\u80fa\uff08DABCO\uff09\uff1a\u8001\u724c\u52b2\u65c5\uff0c\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u4f46\u6c14\u5473\u523a\u9f3b\uff0c\u4e14\u6613\u5bfc\u81f4\u6ce1\u6cab\u6536\u7f29\u3002<\/li>\n
- \u4e94\u7532\u57fa\u4e8c\u4e9a\u4e59\u57fa\u4e09\u80fa\uff08PMDETA\uff09\uff1a\u6d3b\u6027\u9ad8\uff0c\u4f46\u9009\u62e9\u6027\u5dee\uff0c\u6613\u9020\u6210\u51dd\u80f6\u8fc7\u5feb\u3002<\/li>\n
- \u53cc\uff082-\u4e8c\u7532\u6c28\u57fa\u4e59\u57fa\uff09\u919a\uff08BDMAEE\uff09\uff1a\u4f4e\u6c14\u5473\uff0c\u9002\u5408\u6c11\u7528\uff0c\u4f46\u6210\u672c\u9ad8\u3002<\/li>\n<\/ul>\n
\u76f8\u6bd4\u4e4b\u4e0b\uff0cTMEDA\u5728\u6d3b\u6027\u3001\u9009\u62e9\u6027\u3001\u6210\u672c\u4e4b\u95f4\u53d6\u5f97\u4e86\u826f\u597d\u5e73\u8861\uff0c\u582a\u79f0\u201c\u6027\u4ef7\u6bd4\u4e4b\u738b\u201d\u3002\u5c24\u5176\u5728\u9700\u8981\u5feb\u901f\u53d1\u6ce1\u7684\u573a\u5408\uff0c\u5b83\u5f80\u5f80\u662f\u9996\u9009\u3002<\/p>\n
\u4e03\u3001\u4f7f\u7528\u6280\u5de7\uff1a\u5982\u4f55\u8ba9TMEDA\u53d1\u6325\u5927\u5a01\u529b\uff1f<\/p>\n
- \n
- \n
\u7528\u91cf\u63a7\u5236\uff1a\u4e00\u822c\u63a8\u83500.5\u20131.5 pphp\u3002\u8fc7\u91cf\u4f1a\u5bfc\u81f4\u6ce1\u6cab\u5f00\u5b54\u8fc7\u5ea6\uff0c\u5f3a\u5ea6\u4e0b\u964d\u3002\n<\/li>\n
- \n
\u590d\u914d\u4f7f\u7528\uff1a\u53ef\u4e0e\u9521\u7c7b\u50ac\u5316\u5242\uff08\u5982DBTDL\uff09\u642d\u914d\uff0c\u5b9e\u73b0\u201c\u53d1\u6ce1-\u51dd\u80f6\u201d\u534f\u540c\u3002\u5178\u578b\u914d\u65b9\uff1aTMEDA 0.8 pphp + DBTDL 0.1 pphp\u3002\n<\/li>\n
- \n
\u6e29\u5ea6\u5f71\u54cd\uff1aTMEDA\u572820\u201340\u00b0C\u8303\u56f4\u5185\u6d3b\u6027\u4f73\u3002\u6e29\u5ea6\u8fc7\u4f4e\uff0c\u50ac\u5316\u6548\u679c\u51cf\u5f31\uff1b\u8fc7\u9ad8\u5219\u53ef\u80fd\u5f15\u53d1\u526f\u53cd\u5e94\u3002\n<\/li>\n
- \n
\u50a8\u5b58\u6ce8\u610f\uff1a\u5bc6\u5c01\u3001\u907f\u5149\u3001\u5e72\u71e5\u3002\u5f00\u5c01\u540e\u5c3d\u5feb\u4f7f\u7528\uff0c\u907f\u514d\u5438\u6c34\u964d\u89e3\u3002\n<\/li>\n<\/ol>\n
\u516b\u3001\u5b89\u5168\u4e0e\u73af\u4fdd\uff1a\u4fa0\u5ba2\u4e5f\u6709\u8f6f\u808b<\/p>\n
TMEDA\u867d\u5f3a\uff0c\u4f46\u4e0d\u53ef\u201c\u6ee5\u7528\u201d\u3002\u5176LD50\uff08\u5927\u9f20\u7ecf\u53e3\uff09\u7ea6\u4e3a1000 mg\/kg\uff0c\u5c5e\u4e2d\u7b49\u6bd2\u6027\u3002\u5438\u5165\u6216\u76ae\u80a4\u63a5\u89e6\u53ef\u80fd\u5f15\u8d77\u523a\u6fc0\u3002\u64cd\u4f5c\u65f6\u5e94\u4f69\u6234\u9632\u62a4\u624b\u5957\u3001\u53e3\u7f69\uff0c\u5728\u901a\u98ce\u826f\u597d\u5904\u8fdb\u884c\u3002<\/p>\n
\u73af\u4fdd\u65b9\u9762\uff0cTMEDA\u53ef\u751f\u7269\u964d\u89e3\uff0c\u4f46\u9700\u6ce8\u610f\u5176\u78b1\u6027\u53ef\u80fd\u5f71\u54cd\u5e9f\u6c34pH\u3002\u5efa\u8bae\u5904\u7406\u524d\u4e2d\u548c\u3002<\/p>\n
\u4e5d\u3001\u672a\u6765\u5c55\u671b\uff1a\u8001\u5c06\u65b0\u7bc7<\/p>\n
\u968f\u7740\u73af\u4fdd\u6cd5\u89c4\u8d8b\u4e25\uff0c\u4f4eVOC\u3001\u4f4e\u6c14\u5473\u50ac\u5316\u5242\u6210\u4e3a\u8d8b\u52bf\u3002TMEDA\u867d\u6709\u4e00\u5b9a\u6c14\u5473\uff0c\u4f46\u56e0\u5176\u9ad8\u6548\u6027\uff0c\u4ecd\u5728\u4e0d\u65ad\u4f18\u5316\u3002\u76ee\u524d\u5df2\u6709\u4f01\u4e1a\u5f00\u53d1\u51fa\u5fae\u80f6\u56ca\u5316TMEDA\uff0c\u6216\u5c06\u5176\u63a5\u679d\u5230\u9ad8\u5206\u5b50\u8f7d\u4f53\u4e0a\uff0c\u5b9e\u73b0\u7f13\u91ca\u3001\u4f4e\u6325\u53d1\u3002<\/p>\n
\u6b64\u5916\uff0c\u5728\u751f\u7269\u57fa\u805a\u6c28\u916f\u3001\u6c34\u6027\u805a\u6c28\u916f\u7b49\u65b0\u5174\u9886\u57df\uff0cTMEDA\u7684\u50ac\u5316\u673a\u5236\u4e5f\u5728\u88ab\u91cd\u65b0\u7814\u7a76\u3002\u6709\u5b66\u8005\u53d1\u73b0\uff0c\u5b83\u5728\u6c34\u6027\u4f53\u7cfb\u4e2d\u80fd\u6709\u6548\u7a33\u5b9a\u4e73\u6db2\uff0c\u9632\u6b62\u7834\u4e73\uff0c\u5c55\u73b0\u51fa\u65b0\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n
\u5341\u3001\u7ed3\u8bed\uff1a\u81f4\u656c\u8fd9\u4f4d\u201c\u6c89\u9ed8\u7684\u52a0\u901f\u8005\u201d<\/p>\n
\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff0c\u6ca1\u6709\u805a\u6c28\u916f\u6811\u8102\u90a3\u4e48\u98ce\u5149\uff0c\u4e5f\u4e0d\u50cf\u5f02\u6c30\u9178\u916f\u90a3\u6837\u201c\u5371\u9669\u8ff7\u4eba\u201d\uff0c\u4f46\u5b83\u5c31\u50cf\u4e00\u4f4d\u9ed8\u9ed8\u65e0\u95fb\u7684\u5de5\u7a0b\u5e08\uff0c\u7528\u81ea\u5df1\u7cbe\u51c6\u7684\u50ac\u5316\u6280\u827a\uff0c\u8ba9\u65e0\u6570\u6ce1\u6cab\u201c\u4e00\u98de\u51b2\u5929\u201d\u3002\u5b83\u4e0d\u55a7\u54d7\uff0c\u81ea\u6709\u58f0\uff1b\u4e0d\u5f20\u626c\uff0c\u5374\u4e0d\u53ef\u6216\u7f3a\u3002<\/p>\n
\u5728\u6bcf\u4e00\u4e2a\u6e05\u6668\u88ab\u67d4\u8f6f\u5e8a\u57ab\u5524\u9192\u7684\u65f6\u523b\uff0c\u5728\u6bcf\u4e00\u6b21\u9677\u8fdb\u6c99\u53d1\u7684\u60ec\u610f\u77ac\u95f4\uff0c\u6211\u4eec\u6216\u8bb8\u4e0d\u4f1a\u60f3\u8d77TMEDA\uff0c\u4f46\u5b83\u65e9\u5df2\u5728\u5316\u5b66\u7684\u5fae\u89c2\u4e16\u754c\u91cc\uff0c\u5b8c\u6210\u4e86\u4e00\u573a\u60ca\u5fc3\u52a8\u9b44\u7684\u201c\u901f\u5ea6\u9769\u547d\u201d\u3002<\/p>\n
\u5b83\u4e0d\u662f\u4e3b\u89d2\uff0c\u5374\u662f\u8ba9\u4e3b\u89d2\u7cbe\u5f69\u7684\u5173\u952e\u914d\u89d2\u3002<\/p>\n
\u6b63\u5982\u4e00\u4f4d\u8001\u5316\u5de5\u4eba\u6240\u8bf4\uff1a\u201c\u53d1\u6ce1\u8fd9\u4e8b\u513f\uff0c\u4e09\u5206\u9760\u6599\uff0c\u4e03\u5206\u9760\u50ac\u3002TMEDA\uff0c\u5c31\u662f\u90a3\u4e2a\u2018\u50ac\u2019\u5f97\u6070\u5230\u597d\u5904\u7684\u4eba\u3002\u201d<\/p>\n
\u53c2\u8003\u6587\u732e\uff1a<\/p>\n
- \n
- \n
Ulrich, H. (1996). Chemistry and Technology of Isocyanates<\/em>. John Wiley & Sons.
\n\u2014\u2014 \u7ecf\u5178\u4e4b\u4f5c\uff0c\u7cfb\u7edf\u9610\u8ff0\u5f02\u6c30\u9178\u916f\u53cd\u5e94\u673a\u7406\uff0c\u5bf9\u50ac\u5316\u5242\u4f5c\u7528\u6709\u6df1\u5165\u5206\u6790\u3002\n<\/li>\n- \n
K. Oertel (Ed.). (2014). Polyurethane Handbook<\/em> (3rd ed.). Hanser Publishers.
\n\u2014\u2014 \u6743\u5a01\u624b\u518c\uff0c\u6db5\u76d6\u805a\u6c28\u916f\u5168\u9886\u57df\uff0c\u50ac\u5316\u5242\u7ae0\u8282\u8be6\u5b9e\u53ef\u9760\u3002\n<\/li>\n- \n
\u674e\u7ecd\u96c4, \u6731\u5415\u6c11. (1996). \u300a\u805a\u6c28\u916f\u6811\u8102\u300b. \u6c5f\u82cf\u79d1\u5b66\u6280\u672f\u51fa\u7248\u793e.
\n\u2014\u2014 \u56fd\u5185\u805a\u6c28\u916f\u9886\u57df\u7684\u5960\u57fa\u6027\u8457\u4f5c\uff0c\u5bf9TMEDA\u7b49\u50ac\u5316\u5242\u6709\u5b9e\u7528\u4ecb\u7ecd\u3002\n<\/li>\n- \n
Feng, Y., et al. (2020). "Catalytic mechanism of tertiary amines in water-isocyanate reaction for polyurethane foam formation." Polymer<\/em>, 203, 122789.
\n\u2014\u2014 \u8fd1\u5e74\u9ad8\u6c34\u5e73\u7814\u7a76\uff0c\u901a\u8fc7DFT\u8ba1\u7b97\u63ed\u793a\u53d4\u80fa\u50ac\u5316\u673a\u7406\u3002\n<\/li>\n- \n
Zhang, L., et al. (2018). "Effect of TMEDA on the kinetics of polyurethane foam formation." Journal of Cellular Plastics<\/em>, 54(4), 621\u2013635.
\n\u2014\u2014 \u5b9e\u9a8c\u7814\u7a76TMEDA\u5bf9\u53d1\u6ce1\u52a8\u529b\u5b66\u7684\u5f71\u54cd\uff0c\u6570\u636e\u8be6\u5b9e\u3002\n<\/li>\n- \n
\u5434\u57f9\u7199, \u7b49. (2005). \u300a\u805a\u6c28\u916f\u6ce1\u6cab\u5851\u6599\u300b. \u5316\u5b66\u5de5\u4e1a\u51fa\u7248\u793e.
\n\u2014\u2014 \u56fd\u5185\u6ce1\u6cab\u9886\u57df\u6743\u5a01\u53c2\u8003\u4e66\uff0c\u6db5\u76d6\u50ac\u5316\u5242\u9009\u62e9\u4e0e\u5e94\u7528\u3002\n<\/li>\n- \n
Saunders, K. J., & Frisch, K. C. (1962). Polyurethanes: Chemistry and Technology<\/em>. Wiley-Interscience.
\n\u2014\u2014 \u805a\u6c28\u916f\u9886\u57df\u7684\u5f00\u5c71\u4e4b\u4f5c\uff0c\u81f3\u4eca\u4ecd\u6709\u6781\u9ad8\u53c2\u8003\u4ef7\u503c\u3002\n<\/li>\n- \n
Liu, H., et al. (2021). "Recent advances in amine catalysts for polyurethane foams: A review." Progress in Organic Coatings<\/em>, 158, 106342.
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====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n
\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n
\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n
\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n
\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n
===========================================================<\/p>\n
\u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n
- \n
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NT CAT T-12 \u9002\u7528\u4e8e\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff0c\u5feb\u901f\u56fa\u5316\u3002<\/h3>\n<\/li>\n
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NT CAT UL1 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6d3b\u6027\u7565\u4f4e\u4e8eT-12\u3002<\/h3>\n<\/li>\n
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NT CAT UL22 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\uff0c\u4f18\u5f02\u7684\u8010\u6c34\u89e3\u6027\u80fd\u3002<\/h3>\n<\/li>\n
- \n
NT CAT UL28 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u6d3b\u6027\u9ad8\uff0c\u5e38\u7528\u4e8e\u66ff\u4ee3T-12\u3002<\/h3>\n<\/li>\n
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NT CAT UL30 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
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NT CAT UL50 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
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- \n
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