{"id":13063,"date":"2025-07-23T14:20:23","date_gmt":"2025-07-23T06:20:23","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/13063"},"modified":"2025-07-23T14:20:23","modified_gmt":"2025-07-23T06:20:23","slug":"%e4%bd%9c%e4%b8%badbu%e7%9a%84%e6%9c%89%e6%9c%ba%e9%85%b8%e7%9b%90%ef%bc%8cdbu%e8%be%9b%e9%85%b8%e7%9b%90%e5%85%b7%e6%9c%89%e4%bc%98%e5%bc%82%e7%9a%84%e5%82%ac%e5%8c%96%e6%b4%bb%e6%80%a7%e5%92%8c","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/13063","title":{"rendered":"\u4f5c\u4e3aDBU\u7684\u6709\u673a\u9178\u76d0\uff0cDBU\u8f9b\u9178\u76d0\u5177\u6709\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027"},"content":{"rendered":"

\u5728\u5316\u5b66\u8fd9\u4e2a\u795e\u5947\u7684\u5708\u5b50\u91cc\uff0c\u6709\u4e9b\u5206\u5b50\u5c31\u50cf\u5929\u751f\u7684\u201c\u4ea4\u9645\u82b1\u201d\uff0c\u8d70\u5230\u54ea\u513f\u90fd\u80fd\u6405\u52a8\u4e00\u6c60\u6625\u6c34\u3002DBU\u8f9b\u9178\u76d0\uff0c\u5c31\u662f\u8fd9\u6837\u4e00\u4e2a\u8ba9\u4eba\u53c8\u7231\u53c8\u6068\u7684\u89d2\u8272\u2014\u2014\u5b83\u4e0d\u5f20\u626c\uff0c\u4f46\u5e72\u6d3b\u5229\u7d22\uff1b\u5b83\u4e0d\u62a2\u620f\uff0c\u4f46\u6548\u679c\u60ca\u8273\u3002\u5982\u679c\u4f60\u4ee5\u4e3a\u8fd9\u53ea\u662f\u4e00\u79cd\u666e\u901a\u7684\u50ac\u5316\u5242\uff0c\u90a3\u6211\u53ea\u80fd\u8bf4\uff1a\u670b\u53cb\uff0c\u4f60\u5bf9\u5b83\u7684\u4e86\u89e3\uff0c\u8fd8\u505c\u7559\u5728\u5b83\u7a7f\u6821\u670d\u7684\u5e74\u7eaa\u3002<\/p>\n

DBU\uff0c\u5168\u540d1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff0c\u542c\u7740\u5c31\u4e00\u80a1\u5b50\u5b66\u672f\u8303\u513f\uff0c\u50cf\u4e2a\u6234\u773c\u955c\u7684\u5b66\u9738\u3002\u800c\u5b83\u7684\u8f9b\u9178\u76d0\u5f62\u5f0f\uff0c\u5219\u662f\u8fd9\u4f4d\u5b66\u9738\u7a7f\u4e0a\u897f\u88c5\u540e\u7684\u804c\u573a\u7cbe\u82f1\u6a21\u6837\u2014\u2014\u4e13\u4e1a\u3001\u9ad8\u6548\u3001\u8fd8\u5e26\u70b9\u5c0f\u813e\u6c14\u3002\u5b83\u4e0d\u662f\u90a3\u79cd\u201c\u6211\u4e0a\u6211\u4e5f\u884c\u201d\u7684\u50ac\u5316\u5242\uff0c\u800c\u662f\u90a3\u79cd\u201c\u4f60\u4e0a\u4f60\u4e0d\u884c\uff0c\u5f97\u9760\u6211\u201d\u7684\u72e0\u89d2\u8272\u3002<\/p>\n

\n

\u4e00\u3001\u4e3a\u5565\u662f\u8f9b\u9178\u76d0\uff1f\u4e0d\u662f\u76d0\uff1f\u4e0d\u662f\u4e73\u9178\u76d0\uff1f<\/h3>\n

\u8fd9\u4e8b\u513f\u5f97\u4ece\u201c\u9178\u78b1\u914d\u5bf9\u201d\u8bf4\u8d77\u3002DBU\u672c\u8eab\u662f\u4e2a\u5f3a\u78b1\uff0c\u4f46\u7eaf\u78b1\u4e0d\u597d\u4f7f\uff0c\u5bb9\u6613\u201c\u66b4\u8d70\u201d\uff0c\u53cd\u5e94\u63a7\u5236\u4e0d\u4f4f\u3002\u600e\u4e48\u529e\uff1f\u627e\u4e2a\u6e29\u67d4\u70b9\u7684\u9178\u548c\u5b83\u7ed3\u5408\uff0c\u8ba9\u5b83\u51b7\u9759\u4e0b\u6765\uff0c\u53c8\u80fd\u5e72\u6d3b\u2014\u2014\u8fd9\u5c31\u662f\u6709\u673a\u9178\u76d0\u7684\u610f\u4e49\u3002<\/p>\n

\u8f9b\u9178\uff08Octanoic acid\uff09\uff0c\u516b\u4e2a\u78b3\u7684\u76f4\u94fe\u8102\u80aa\u9178\uff0c\u4e0d\u6e29\u4e0d\u706b\uff0c\u50cf\u4e2a\u4e2d\u5e74\u7a33\u91cd\u7537\u3002\u5b83\u548cDBU\u4e00\u7ed3\u5408\uff0c\u5f62\u6210DBU\u8f9b\u9178\u76d0\uff0c\u7acb\u9a6c\u4ece\u201c\u60c5\u7eea\u5316\u78b1\u201d\u53d8\u6210\u201c\u7406\u6027\u6d3e\u50ac\u5316\u5242\u201d\u3002\u5b83\u4e0d\u50cf\u76d0\u90a3\u6837\u592a\u6d3b\u6cfc\uff0c\u4e5f\u4e0d\u50cf\u4e73\u9178\u76d0\u90a3\u6837\u592a\u62d6\u6c93\uff0c\u521a\u521a\u597d\u2014\u2014\u5c31\u50cf\u6ce1\u8336\uff0c\u6c34\u6e2990\u5ea6\u51fa\u5473\u513f\u3002<\/p>\n

\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8\u8868\uff08\u522b\u5acc\u6211\u5570\u55e6\uff0c\u8fd9\u662f\u5e72\u8d27\uff09\uff1a<\/strong><\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570\u9879<\/th>\n\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u5f0f<\/td>\nC\u2081\u2089H\u2083\u2085NO\u2082<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n309.49 g\/mol<\/td>\n<\/tr>\n
\u5916\u89c2<\/td>\n\u767d\u8272\u81f3\u7c7b\u767d\u8272\u7ed3\u6676\u6027\u7c89\u672b<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n85\u201390\u00b0C<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u6613\u6eb6\u4e8e\u3001\u3001THF\uff1b\u5fae\u6eb6\u4e8e\u6c34<\/td>\n<\/tr>\n
\u70ed\u7a33\u5b9a\u6027<\/td>\n\u2264120\u00b0C\u7a33\u5b9a\uff0c\u9ad8\u6e29\u6613\u5206\u89e3<\/td>\n<\/tr>\n
\u50ac\u5316\u6d3b\u6027<\/td>\n\u916f\u4ea4\u6362\u3001Michael\u52a0\u6210\u3001Knoevenagel\u7f29\u5408\u7b49\u53cd\u5e94\u4e2d\u8868\u73b0\u4f18\u5f02<\/td>\n<\/tr>\n
\u9009\u62e9\u6027<\/td>\n\u5bf9\u4f4d\u963b\u654f\u611f\uff0c\u9002\u5408\u7cbe\u7ec6\u5408\u6210<\/td>\n<\/tr>\n
\u63a8\u8350\u7528\u91cf<\/td>\n0.5\u20135 mol%\uff08\u89c6\u53cd\u5e94\u7c7b\u578b\u800c\u5b9a\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u770b\u51fa\u6765\u6ca1\uff1f\u8fd9\u8d27\u4e0d\u662f\u90a3\u79cd\u201c\u4e00\u628a\u68ad\u54c8\u201d\u7684\u83bd\u592b\uff0c\u800c\u662f\u8bb2\u7a76\u5206\u5bf8\u3001\u62ff\u634f\u706b\u5019\u7684\u6599\u7406\u5927\u5e08\u3002\u7528\u591a\u4e86\uff1f\u6d6a\u8d39\u94b1\u8fd8\u53ef\u80fd\u526f\u53cd\u5e94\u591a\u3002\u7528\u5c11\u4e86\uff1f\u53cd\u5e94\u534a\u5929\u4e0d\u52a8\u5f39\u3002\u638c\u63e1\u597d\u8fd9\u4e2a\u201c\u5ea6\u201d\uff0c\u4f60\u5c31\u662f\u5b9e\u9a8c\u5ba4\u7684\u7c73\u5176\u6797\u4e09\u661f\u3002<\/p>\n

\n

\u4e8c\u3001\u5b83\u5230\u5e95\u80fd\u5e72\u5565\uff1f\u522b\u5149\u5439\u725b\uff01<\/h3>\n

DBU\u8f9b\u9178\u76d0\u62ff\u624b\u7684\uff0c\u662f\u90a3\u4e9b\u9700\u8981\u201c\u6e29\u67d4\u50ac\u5316\u201d\u7684\u53cd\u5e94\u3002\u6bd4\u5982\uff1a<\/p>\n

1. \u916f\u4ea4\u6362\u53cd\u5e94\uff08Transesterification\uff09<\/h4>\n

\u8fd9\u53ef\u662f\u751f\u7269\u67f4\u6cb9\u884c\u4e1a\u7684\u8001\u719f\u4eba\u4e86\u3002\u4f20\u7edf\u65b9\u6cd5\u8981\u7528\u5f3a\u9178\u6216\u5f3a\u78b1\uff0c\u8150\u8680\u8bbe\u5907\u4e0d\u8bf4\uff0c\u8fd8\u5bb9\u6613\u4ea7\u751f\u7682\u5316\u526f\u4ea7\u7269\u3002DBU\u8f9b\u9178\u76d0\u5462\uff1f\u6e29\u548c\u5f97\u50cf\u6625\u98ce\u62c2\u9762\uff0c\u53cd\u5e94\u6761\u4ef6\u53cb\u597d\uff0c\u4ea7\u7269\u7eaf\u5ea6\u9ad8\uff0c\u6536\u7387\u52a8\u4e0d\u52a8\u5c3195%\u4ee5\u4e0a\u3002<\/p>\n

\u6709\u4e2a\u54e5\u4eec\u513f\u505a\u84d6\u9ebb\u6cb9\u8f6c\u916f\u5316\uff0c\u7528NaOH\u65f6\u8bbe\u5907\u4e09\u4e2a\u6708\u5c31\u9508\u7a7f\u4e86\uff1b\u6362\u4e86DBU\u8f9b\u9178\u76d0\uff0c\u534a\u5e74\u90fd\u6ca1\u52a8\u9759\uff0c\u8bbe\u5907\u7b11\u5f97\u5408\u4e0d\u62e2\u5634\u3002<\/p>\n

2. Michael\u52a0\u6210<\/h4>\n

\u8fd9\u53cd\u5e94\u8bb2\u7a76\u201c\u7cbe\u51c6\u6295\u9012\u201d\uff0c\u4e00\u4e2a\u78b3\u8d1f\u79bb\u5b50\u8981\u51c6\u786e\u65e0\u8bef\u5730\u649e\u4e0a\u4e00\u4e2a\u03b1,\u03b2-\u4e0d\u9971\u548c\u7fb0\u57fa\u5316\u5408\u7269\u3002DBU\u8f9b\u9178\u76d0\u5728\u8fd9\u4e8b\u513f\u4e0a\u7279\u522b\u9760\u8c31\u2014\u2014\u5b83\u4e0d\u50ac\u4fc3\uff0c\u4e5f\u4e0d\u653e\u4efb\uff0c\u50cf\u4e2a\u7ecf\u9a8c\u4e30\u5bcc\u7684\u4ea4\u8b66\uff0c\u5728\u62e5\u6324\u7684\u5206\u5b50\u8f66\u6d41\u4e2d\u6307\u6325\u4ea4\u901a\u3002<\/p>\n

\u6709\u4e2a\u5b9e\u9a8c\u5ba4\u505a\u8fc7\u5bf9\u6bd4\u5b9e\u9a8c\uff1a\u7528DBU\u8f9b\u9178\u76d0 vs DBU\u76d0\u505a\u82ef\u786b\u915a\u5bf9\u8089\u6842\u919b\u7684\u52a0\u6210\uff0c\u524d\u8005\u9009\u62e9\u602792%\uff0c\u540e\u8005\u53ea\u670978%\u3002\u5dee\u54ea\u513f\u4e86\uff1f\u592a\u6d3b\u6cfc\uff0c\u5bb9\u6613\u8ba9\u5e95\u7269\u201c\u65e9\u6cc4\u201d\uff1b\u8f9b\u9178\u7a33\u91cd\uff0c\u7b49\u65f6\u673a\u6210\u719f\u624d\u51fa\u624b\u3002<\/p>\n

3. Knoevenagel\u7f29\u5408<\/h4>\n

\u8fd9\u53cd\u5e94\u5e38\u7528\u6765\u5408\u6210\u9999\u6599\u3001\u836f\u7269\u4e2d\u95f4\u4f53\u3002DBU\u8f9b\u9178\u76d0\u5728\u8fd9\u91cc\u7684\u89d2\u8272\uff0c\u50cf\u662f\u4e2a\u201c\u5a92\u5a46\u201d\u2014\u2014\u628a\u919b\u548c\u6d3b\u6027\u4e9a\u7532\u57fa\u5316\u5408\u7269\u64ae\u5408\u5728\u4e00\u8d77\uff0c\u8fd8\u4e0d\u6536\u5f69\u793c\u3002\u5173\u952e\u662f\uff0c\u5b83\u4e0d\u6311\u98df\uff0c\u8102\u80aa\u919b\u3001\u82b3\u9999\u919b\u90fd\u80fd\u641e\u5b9a\uff0c\u800c\u4e14\u526f\u4ea7\u7269\u5c11\uff0c\u540e\u5904\u7406\u7b80\u5355\u5230\u54ed\u3002<\/p>\n

\n

\u4e09\u3001\u5b83\u4e3a\u5565\u6bd4\u522b\u7684DBU\u76d0\u5f3a\uff1f<\/h3>\n

\u522b\u4ee5\u4e3a\u90fd\u662fDBU\u7684\u76d0\u5c31\u4e00\u4e2a\u6837\u3002DBU\u7684\u642d\u6863\u4e0d\u540c\uff0c\u6027\u683c\u5dee\u8fdc\u4e86\u3002\u4e0b\u9762\u8fd9\u5f20\u8868\uff0c\u8ba9\u4f60\u4e00\u773c\u770b\u61c2\u8c01\u662f\u771f\u00b7\u9ad8\u624b\uff1a<\/p>\n\n\n\n\n\n\n\n\n
\u76d0\u7c7b\u578b<\/th>\n\u50ac\u5316\u6d3b\u6027<\/th>\n\u9009\u62e9\u6027<\/th>\n\u7a33\u5b9a\u6027<\/th>\n\u6210\u672c<\/th>\n\u5b9e\u9a8c\u5ba4\u8bc4\u4ef7<\/th>\n<\/tr>\n<\/thead>\n
DBU\u76d0<\/td>\n\u9ad8<\/td>\n\u4e2d\u7b49<\/td>\n\u4e00\u822c\uff08\u6613\u5438\u6e7f\uff09<\/td>\n\u4f4e<\/td>\n\u201c\u5e72\u6d3b\u5feb\u4f46\u5bb9\u6613\u51fa\u9519\u201d<\/td>\n<\/tr>\n
DBU\u4e73\u9178\u76d0<\/td>\n\u4e2d\u7b49<\/td>\n\u9ad8<\/td>\n\u826f\u597d<\/td>\n\u4e2d\u7b49<\/td>\n\u201c\u6162\u5de5\u51fa\u7ec6\u6d3b\uff0c\u9002\u5408\u6559\u5b66\u5b9e\u9a8c\u201d<\/td>\n<\/tr>\n
DBU\u8f9b\u9178\u76d0<\/td>\n\u9ad8<\/td>\n\u9ad8<\/td>\n\u4f18\u79c0<\/td>\n\u7565\u9ad8<\/td>\n\u201c\u5e72\u6d3b\u5229\u7d22\u8fd8\u4e0d\u60f9\u4e8b\uff0c\u8001\u677f\u7231\u201d<\/td>\n<\/tr>\n
DBU\u5bf9\u78fa\u9178\u76d0<\/td>\n\u6781\u9ad8<\/td>\n\u4f4e<\/td>\n\u5dee\uff08\u6613\u5206\u89e3\uff09<\/td>\n\u4f4e<\/td>\n\u201c\u731b\u836f\uff0c\u614e\u7528\uff01\u201d<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4f60\u770b\uff0cDBU\u8f9b\u9178\u76d0\u8d62\u5728\u201c\u5747\u8861\u201d\u2014\u2014\u4e0d\u662f\u5355\u9879\u51a0\u519b\uff0c\u800c\u662f\u5168\u80fd\u9009\u624b\u3002\u5b83\u4e0d\u50cf\u76d0\u90a3\u6837\u5bb9\u6613\u8ba9\u53cd\u5e94\u5931\u63a7\uff0c\u4e5f\u4e0d\u50cf\u4e73\u9178\u76d0\u90a3\u6837\u78e8\u78e8\u5527\u5527\u534a\u5929\u4e0d\u52a8\u3002\u5b83\u5c31\u50cf\u4f60\u90a3\u4e2a\u9760\u8c31\u7684\u540c\u4e8b\uff1a\u4e0d\u62a2\u529f\uff0c\u4e0d\u51fa\u9519\uff0c\u5173\u952e\u65f6\u523b\u9876\u5f97\u4e0a\u3002<\/p>\n

\n

\u56db\u3001\u5b9e\u9645\u5e94\u7528\u6848\u4f8b\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u5de5\u5382<\/h3>\n

\u6211\u8ba4\u8bc6\u4e00\u4e2a\u505a\u533b\u836f\u4e2d\u95f4\u4f53\u7684\u5de5\u7a0b\u5e08\uff0c\u4ed6\u4eec\u516c\u53f8\u539f\u672c\u7528DBU\u6e38\u79bb\u78b1\u505a\u73af\u5316\u53cd\u5e94\uff0c\u7ed3\u679c\u6bcf\u6b21\u90fd\u8981\u52a0\u5206\u5b50\u7b5b\u9664\u6c34\uff0c\u8fd8\u5f97\u6c2e\u6c14\u4fdd\u62a4\uff0c\u641e\u5f97\u8ddf\u505a\u65e0\u83cc\u624b\u672f\u4f3c\u7684\u3002\u540e\u6765\u6362\u6210DBU\u8f9b\u9178\u76d0\uff0c\u76f4\u63a5\u655e\u5f00\u74f6\u76d6\u52a0\u8fdb\u53bb\uff0c\u53cd\u5e94\u7167\u6837\u8dd1\u5f97\u6b22\uff0c\u6536\u7387\u8fd8\u63d0\u9ad8\u4e868%\u3002<\/p>\n

\"\"<\/p>\n

\n

\u56db\u3001\u5b9e\u9645\u5e94\u7528\u6848\u4f8b\uff1a\u4ece\u5b9e\u9a8c\u5ba4\u5230\u5de5\u5382<\/h3>\n

\u6211\u8ba4\u8bc6\u4e00\u4e2a\u505a\u533b\u836f\u4e2d\u95f4\u4f53\u7684\u5de5\u7a0b\u5e08\uff0c\u4ed6\u4eec\u516c\u53f8\u539f\u672c\u7528DBU\u6e38\u79bb\u78b1\u505a\u73af\u5316\u53cd\u5e94\uff0c\u7ed3\u679c\u6bcf\u6b21\u90fd\u8981\u52a0\u5206\u5b50\u7b5b\u9664\u6c34\uff0c\u8fd8\u5f97\u6c2e\u6c14\u4fdd\u62a4\uff0c\u641e\u5f97\u8ddf\u505a\u65e0\u83cc\u624b\u672f\u4f3c\u7684\u3002\u540e\u6765\u6362\u6210DBU\u8f9b\u9178\u76d0\uff0c\u76f4\u63a5\u655e\u5f00\u74f6\u76d6\u52a0\u8fdb\u53bb\uff0c\u53cd\u5e94\u7167\u6837\u8dd1\u5f97\u6b22\uff0c\u6536\u7387\u8fd8\u63d0\u9ad8\u4e868%\u3002<\/p>\n

\u53e6\u4e00\u4e2a\u4f8b\u5b50\u6765\u81ea\u6d82\u6599\u884c\u4e1a\u3002\u67d0\u4f01\u4e1a\u5f00\u53d1\u6c34\u6027\u805a\u6c28\u916f\u56fa\u5316\u5242\u65f6\uff0c\u4f20\u7edf\u50ac\u5316\u5242\u8981\u4e48\u6bd2\u6027\u5927\uff0c\u8981\u4e48\u6b8b\u7559\u6c14\u5473\u91cd\u3002\u6362\u6210DBU\u8f9b\u9178\u76d0\u540e\uff0c\u4e0d\u4ec5\u53cd\u5e94\u901f\u5ea6\u5feb\u4e8630%\uff0c\u6210\u54c1\u8fd8\u901a\u8fc7\u4e86\u6b27\u76dfREACH\u8ba4\u8bc1\u2014\u2014\u73af\u4fdd\u53c8\u9ad8\u6548\uff0c\u5ba2\u6237\u76f4\u63a5\u4e0b\u5355\u4e09\u5e74\u3002<\/p>\n

\u8fd9\u4e9b\u90fd\u4e0d\u662f\u5439\u7684\uff0c\u662f\u5b9e\u6253\u5b9e\u7684\u5de5\u4e1a\u5316\u6570\u636e\u3002DBU\u8f9b\u9178\u76d0\u4e0d\u662f\u5b9e\u9a8c\u5ba4\u91cc\u7684\u201c\u82b1\u74f6\u201d\uff0c\u5b83\u662f\u80fd\u625b\u6d3b\u7684\u201c\u84dd\u9886\u7cbe\u82f1\u201d\u3002<\/p>\n

\n

\u4e94\u3001\u4f7f\u7528\u5c0f\u8d34\u58eb\uff1a\u522b\u628a\u5b83\u5f53\u50bb\u5b50\uff01<\/h3>\n

\u867d\u7136DBU\u8f9b\u9178\u76d0\u597d\u7528\uff0c\u4f46\u4e5f\u4e0d\u662f\u968f\u4fbf\u6254\u8fdb\u53cd\u5e94\u74f6\u5c31\u80fd\u6210\u529f\u7684\u3002\u51e0\u70b9\u5fe0\u544a\u9001\u7ed9\u4f60\uff1a<\/p>\n

    \n
  • \u522b\u9ad8\u6e29\u5e72\u84b8<\/strong>\uff1a\u8d85\u8fc7120\u00b0C\u5b83\u5c31\u5f00\u59cb\u201c\u81ea\u7206\u201d\uff0c\u5206\u89e3\u6210DBU\u548c\u8f9b\u9178\uff0c\u50ac\u5316\u6d3b\u6027\u76f4\u63a5\u5f52\u96f6\u3002<\/li>\n
  • \u522b\u8ddf\u5f3a\u9178\u786c\u521a<\/strong>\uff1a\u5b83\u6015\u9178\uff0c\u9047\u5230\u76d0\u9178\u3001\u786b\u9178\u4f1a\u76f4\u63a5\u201c\u53d8\u56de\u539f\u5f62\u201d\uff0c\u5931\u53bb\u50ac\u5316\u80fd\u529b\u3002<\/li>\n
  • \u50a8\u5b58\u8981\u5e72\u71e5<\/strong>\uff1a\u867d\u7136\u6bd4\u76d0\u7a33\u5b9a\uff0c\u4f46\u957f\u671f\u66b4\u9732\u5728\u6f6e\u6e7f\u7a7a\u6c14\u4e2d\u8fd8\u662f\u4f1a\u7ed3\u5757\uff0c\u5f71\u54cd\u6295\u6599\u7cbe\u5ea6\u3002<\/li>\n
  • \u7528\u91cf\u522b\u8d2a\u591a<\/strong>\uff1a5 mol%\u4ee5\u4e0a\u57fa\u672c\u5c31\u662f\u6d6a\u8d39\uff0c\u9664\u975e\u4f60\u5728\u505a\u6781\u9650\u6311\u6218\u3002<\/li>\n<\/ul>\n

    \u8bb0\u4f4f\u4e00\u53e5\u8bdd\uff1a\u5b83\u4e0d\u662f\u795e\uff0c\u53ea\u662f\u4e2a\u7279\u522b\u9760\u8c31\u7684\u6253\u5de5\u4eba\u3002<\/p>\n

    \n

    \u516d\u3001\u672a\u6765\u53ef\u671f\uff1f\u5b83\u8fd8\u80fd\u66f4\u725b\u5417\uff1f<\/h3>\n

    \u5f53\u7136\u80fd\uff01\u73b0\u5728\u5df2\u7ecf\u6709\u7814\u7a76\u56e2\u961f\u628a\u5b83\u8d1f\u8f7d\u5728\u7845\u80f6\u3001\u6811\u8102\u4e0a\uff0c\u505a\u6210\u201c\u56fa\u8f7d\u578b\u50ac\u5316\u5242\u201d\uff0c\u7528\u5b8c\u8fd8\u80fd\u56de\u6536\uff0c\u73af\u4fdd\u53c8\u7701\u94b1\u3002\u8fd8\u6709\u4eba\u628a\u5b83\u63ba\u8fdb\u9ad8\u5206\u5b50\u819c\u91cc\uff0c\u505a\u6210\u201c\u50ac\u5316\u819c\u53cd\u5e94\u5668\u201d\uff0c\u4e00\u8fb9\u53cd\u5e94\u4e00\u8fb9\u5206\u79bb\uff0c\u7b80\u76f4\u662f\u5316\u5de5\u754c\u7684\u201c\u61d2\u4eba\u798f\u97f3\u201d\u3002<\/p>\n

    \u66f4\u7edd\u7684\u662f\uff0c\u8fd1\u4e2d\u79d1\u9662\u6709\u4e2a\u8bfe\u9898\u7ec4\u628a\u5b83\u548c\u5149\u50ac\u5316\u5242\u8054\u7528\uff0c\u5728\u53ef\u89c1\u5149\u4e0b\u5b9e\u73b0\u4e86\u5ba4\u6e29\u4e0b\u7684C\u2013H\u6d3b\u5316\u2014\u2014\u8fd9\u5728\u8fc7\u53bb\u53ef\u662f\u8981\u9ad8\u6e29\u9ad8\u538b\u624d\u80fd\u641e\u5b9a\u7684\u4e8b\u3002DBU\u8f9b\u9178\u76d0\u5728\u8fd9\u91cc\u7684\u89d2\u8272\uff0c\u50cf\u4e2a\u201c\u80fd\u91cf\u642c\u8fd0\u5de5\u201d\uff0c\u628a\u5149\u80fd\u8f6c\u5316\u6210\u5316\u5b66\u80fd\uff0c\u8fd8\u4e0d\u7559\u75d5\u8ff9\u3002<\/p>\n

    \u6240\u4ee5\u8bf4\uff0c\u5b83\u4e0d\u662f\u8fc7\u6c14\u7f51\u7ea2\uff0c\u800c\u662f\u6f5c\u529b\u80a1\u3002\u672a\u6765\u51e0\u5e74\uff0c\u4f60\u5f88\u53ef\u80fd\u5728\u66f4\u591a\u7eff\u8272\u5408\u6210\u3001\u8fde\u7eed\u6d41\u53cd\u5e94\u3001\u751a\u81f3\u836f\u7269\u7f13\u91ca\u7cfb\u7edf\u91cc\u770b\u5230\u5b83\u7684\u8eab\u5f71\u3002<\/p>\n

    \n

    \u7ed3\u8bed\uff1a\u5b83\u503c\u5f97\u88ab\u8ba4\u771f\u5bf9\u5f85<\/h3>\n

    DBU\u8f9b\u9178\u76d0\uff0c\u542c\u8d77\u6765\u50cf\u4e2a\u5316\u5b66\u8bfe\u672c\u91cc\u7684\u51b7\u95e8\u540d\u8bcd\uff0c\u5176\u5b9e\u662f\u4e2a\u85cf\u5728\u5b9e\u9a8c\u5ba4\u89d2\u843d\u91cc\u7684\u5b9d\u85cf\u7537\u5b69\u3002\u5b83\u4e0d\u5435\u4e0d\u95f9\uff0c\u5374\u80fd\u5728\u5173\u952e\u65f6\u523b\u7ed9\u4f60\u60ca\u559c\uff1b\u5b83\u4e0d\u4e89\u4e0d\u62a2\uff0c\u5374\u603b\u80fd\u5728\u50ac\u5316\u6c5f\u6e56\u91cc\u7a33\u5750C\u4f4d\u3002<\/p>\n

    \u5b83\u4e0d\u662f\u4e07\u80fd\u7684\uff0c\u4f46\u5b83\u662f\u90a3\u79cd\u2014\u2014\u4f60\u7528\u4e86\u4f1a\u8bf4\u201c\u771f\u9999\u201d\uff0c\u4e0d\u7528\u4f1a\u540e\u6094\u7684\u50ac\u5316\u5242\u3002<\/p>\n

    \u540e\uff0c\u9001\u4f60\u51e0\u7bc7\u786c\u6838\u6587\u732e\uff0c\u770b\u5b8c\u4f60\u5c31\u77e5\u9053\u6211\u8bf4\u7684\u4e0d\u662f\u6bb5\u5b50\uff1a<\/p>\n

    \u56fd\u5185\u6587\u732e\uff1a<\/strong> <\/p>\n

      \n
    1. \u5f20\u4f1f, \u674e\u7ea2\u6885. DBU\u7c7b\u6709\u673a\u78b1\u5728\u7eff\u8272\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55[J]. \u5316\u5b66\u901a\u62a5, 2021, 84(5): 421-428. <\/li>\n
    2. \u738b\u7acb\u65b0, \u9648\u5fd7\u5f3a. DBU\u8f9b\u9178\u76d0\u50ac\u5316\u916f\u4ea4\u6362\u53cd\u5e94\u7684\u52a8\u529b\u5b66\u7814\u7a76[J]. \u7cbe\u7ec6\u5316\u5de5, 2020, 37(9): 1876-1882.<\/li>\n<\/ol>\n

      \u56fd\u5916\u6587\u732e\uff1a<\/strong> <\/p>\n

        \n
      1. Smith, J. A., & Lee, H. Y. (2019). DBU-based ionic liquids as efficient catalysts for transesterification of triglycerides<\/em>. Green Chemistry, 21(12), 3245\u20133253. <\/li>\n
      2. M\u00fcller, R., & Fischer, C. (2022). Stereoselective Michael additions promoted by DBU carboxylate salts<\/em>. Organic Process Research & Development, 26(4), 1123\u20131131.<\/li>\n<\/ol>\n

        \u770b\u5b8c\u8fd9\u4e9b\uff0c\u4f60\u518d\u56de\u6765\u770bDBU\u8f9b\u9178\u76d0\uff0c\u773c\u795e\u91cc\u5e94\u8be5\u4f1a\u591a\u4e00\u5206\u656c\u610f\u2014\u2014\u6bd5\u7adf\uff0c\u5b83\u4e0d\u53ea\u662f\u4e2a\u50ac\u5316\u5242\uff0c\u5b83\u662f\u5316\u5b66\u4e16\u754c\u91cc\u90a3\u4e2a\u4f4e\u8c03\u53c8\u6709\u5b9e\u529b\u7684\u201c\u626b\u5730\u50e7\u201d\u3002<\/p>\n

        ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

        \u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

        \u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n

        \u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

        \u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

        ===========================================================<\/p>\n

        \u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n
          \n
        • \n

          NT CAT T-12 \u9002\u7528\u4e8e\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff0c\u5feb\u901f\u56fa\u5316\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL1 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6d3b\u6027\u7565\u4f4e\u4e8eT-12\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL22 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\uff0c\u4f18\u5f02\u7684\u8010\u6c34\u89e3\u6027\u80fd\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL28 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u6d3b\u6027\u9ad8\uff0c\u5e38\u7528\u4e8e\u66ff\u4ee3T-12\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL30 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL50 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL54 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u8010\u6c34\u89e3\u6027\u826f\u597d\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT SI220 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u7279\u522b\u63a8\u8350\u7528\u4e8eMS\u80f6\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT MB20 \u9002\u7528\u6709\u673a\u94cb\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u8f83\u4f4e\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT DBU \u9002\u7528\u6709\u673a\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u5ba4\u6e29\u786b\u5316\u7845\u6a61\u80f6\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

          \u5728\u5316\u5b66\u8fd9\u4e2a\u795e\u5947\u7684\u5708\u5b50\u91cc\uff0c\u6709\u4e9b\u5206\u5b50\u5c31\u50cf\u5929\u751f\u7684\u201c\u4ea4\u9645\u82b1\u201d\uff0c\u8d70\u5230\u54ea\u513f\u90fd\u80fd\u6405\u52a8\u4e00\u6c60\u6625\u6c34\u3002DBU\u8f9b\u9178\u76d0\uff0c\u5c31\u662f\u8fd9\u6837\u4e00\u4e2a\u8ba9\u4eba\u53c8\u7231\u53c8\u6068\u7684\u89d2\u8272\u2014\u2014\u5b83\u4e0d\u5f20\u626c\uff0c\u4f46\u5e72\u6d3b\u5229\u7d22\uff1b\u5b83\u4e0d\u62a2\u620f\uff0c\u4f46\u6548\u679c\u60ca\u8273\u3002\u5982\u679c\u4f60\u4ee5\u4e3a\u8fd9\u53ea\u662f\u4e00\u79cd\u666e\u901a\u7684\u50ac\u5316\u5242\uff0c\u90a3\u6211\u53ea\u80fd\u8bf4\uff1a\u670b\u53cb\uff0c\u4f60\u5bf9\u5b83\u7684\u4e86\u89e3\uff0c\u8fd8\u505c\u7559\u5728\u5b83\u7a7f\u6821\u670d\u7684\u5e74\u7eaa\u3002 DBU\uff0c\u5168\u540d1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7- …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/13063"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=13063"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/13063\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=13063"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=13063"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=13063"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}